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What are the chemical properties of 1-Chlorododecane?
1-Chlorododecane is also an organic compound. Its properties are stable, it is a colorless liquid at room temperature and pressure, and has a weak aromatic odor.
The chemical properties of 1-chlorododecane are mainly due to its nucleophilic substitution reaction. Due to the high electronegativity of the chlorine atom in the molecule, the carbon-chlorine bond is polar, and the carbon atom is partially positively charged, which is vulnerable to attack by nucleophilic reagents. For example, when co-heated with an aqueous solution of sodium hydroxide, the chlorine atom is replaced by a hydroxyl group to form a dodecanol. The reaction formula is as follows: C -2 H ² Cl + NaOH → C -2 H ² OH + NaCl. This reaction is often an important way to prepare alcohols in organic synthesis.
Furthermore, 1-chlorododecane can participate in the elimination reaction. Under the action of strong bases such as sodium alcohol solution, a reaction to eliminate hydrogen chloride occurs, resulting in dodecene. This reaction condition needs to be properly controlled. If the temperature is too high or the concentration of the base is too large, or the side reaction increases. The reaction formula is: C ³ H ² Cl + C ² H ONa → C ³ H ² + C ² H OH + NaCl.
In addition, 1-chlorododecane can undergo a free radical substitution reaction in the presence of light or a free radical initiator. The hydrogen atom on the α-carbon atom connected to the chlorine atom in the molecule can be replaced by the halogen atom to form a polyhalogenated product under light conditions. This reaction process involves the generation, growth and termination of free radicals.
And because of its long carbon chain in the molecule, it has certain hydrophobicity, good solubility in organic solvents, slightly soluble in water. And the chemical properties are relatively stable, and it can be stored for a long time at room temperature and pressure, but it should be avoided from contact with strong oxidants, strong bases and other substances to prevent chemical reactions.
What are the common uses of 1-Chlorododecane?
1-Chlorododecane has three common uses. One is in the synthesis of surfactants. Surfactants are heavy in daily use and industry, such as detergents, emulsifiers, etc. 1-Chlorododecane can be reacted to make cationic, anionic, and non-ionic surfactants. If it reacts with amines, it becomes a cationic surfactant, which has good emulsification and antistatic properties. It is commonly used in textile and plastic processing. The second is used to prepare plasticizers. Plasticizers can increase polymer flexibility and plasticity. 1-Chlorododecane reacts with alcohols and acids to form ester plasticizers, such as di (dodecyl) phthalate, which is used in plastics such as polyvinyl chloride to improve its processing performance and product toughness. The third can be used as an organic synthesis intermediate. Due to the presence of chlorine atoms, it is reactive and can participate in reactions such as substitution and elimination to produce complex organic compounds. Such as reacting with sodium cyanide to obtain dodecyl nitrile, which is then hydrolyzed into dodecanoic acid, which is used as a raw material for synthetic fragrances and lubricants. In short, 1-chlorododecane is widely used in the chemical industry and is crucial to the development of many industries.
What is the production method of Chlorododecane?
1-Chlorododecane is also a common raw material in the chemical industry. There are about two methods for its preparation. One is the method of alcohol-halogen replacement, and the other is the technique of olefin addition.
Alcohol-halogen replacement is obtained by the interaction of dodecanol and halogenating agent. Often thionyl chloride, phosphorus trichloride or hydrochloric acid are used as halogenating agents. If thionyl chloride is used, the reaction is mild, the product is pure, and it is easy to separate. During the reaction, the dodecanol and thionyl chloride are heated and stirred in a suitable solvent, such as toluene, dichloromethane, etc. in a certain proportion. The thionyl chloride reacts with the alcohol hydroxyl group to form 1-chlorododecane, sulfur dioxide and hydrogen chloride. Sulfur dioxide and hydrogen chloride escape, and the rest are distilled, washed, dried, and other steps to obtain pure 1-chlorododecane.
The addition of olefins is prepared by the addition of dodecene and hydrogen chloride. This reaction requires the presence of catalysts, such as anhydrous aluminum trichloride, anhydrous zinc chloride, etc. At a certain temperature and pressure, dodecene and hydrogen chloride gas are introduced into the catalyst-containing reactor, the double bonds of the olefins are opened, and hydrogen chloride is added to it to generate 1-chlorododecane. After the reaction, the product is rectified and purified to remove unreacted raw materials and by-products to obtain a pure target product.
When preparing 1-chlorododecane, the purity of the raw material, the reaction conditions such as temperature, pressure, and the amount of catalyst are all related to the yield and quality of the product. Therefore, when preparing, it must be carefully controlled to obtain ideal results.
What is the environmental impact of Chlorododecane?
1-Chlorododecane is an organic compound. Its impact on the environment cannot be underestimated.
This substance has certain toxicity. If it is released in nature or enters the water body, aquatic organisms will bear the brunt. It may interfere with the physiological functions of aquatic organisms, causing growth and reproduction to be hindered. In the food chain, or through bioaccumulation, from plankton to large fish, the concentration gradually increases, and eventually endangers high-end predators.
In the soil environment, 1-chlorododecane may affect the activity and community structure of soil microorganisms. Microorganisms are essential for soil material circulation and nutrient transformation. If they are disturbed, the soil ecological balance will also be destroyed, or the soil fertility will decrease, affecting the growth of vegetation.
In the atmosphere, after 1-chlorododecane evaporates, or participates in photochemical reactions, it affects the chemical composition of the atmosphere, has a negative effect on air quality, or involves complex atmospheric processes such as ozone generation, and indirectly affects climate and human health.
And the chemical properties of 1-chlorododecane are relatively stable, and the natural degradation is slow. If it persists in the environment for a long time, it will continue to release hazards, expand the scope of pollution, and increase the difficulty of control. Therefore, its production, use and emission should be strictly controlled to reduce its harm to the environment and ensure ecological safety.
What should I pay attention to when storing and shipping Chlorododecane?
1-Chlorododecane is also an organic compound. During storage and transportation, many matters must be observed.
First word storage. This substance must be stored in a cool and ventilated warehouse. Because high temperature can cause its volatilization to intensify, and may cause chemical reactions, endangering safety. The temperature of the warehouse should be controlled in a specific range, so as not to affect its properties if the temperature is too high or too low. It must also be kept away from fire and heat sources, both of which can cause the risk of combustion or even explosion. Because of its flammability, in case of open flame and high heat energy combustion, fire prevention is a top priority. Furthermore, it should be stored separately from oxidants and alkalis, and must not be mixed. If these substances come into contact with it, they may react violently, damage the substance itself, or even cause a safety accident.
As for transportation, caution is also required. Transportation vehicles must be equipped with corresponding varieties and quantities of fire-fighting equipment and leakage emergency treatment equipment. To prevent emergencies during transportation, such as fire, leakage, etc., can be responded to in time. The tank (tank) car used during transportation should have a grounding chain, and holes can be set in the tank to reduce shock and generate static electricity. Due to the accumulation of static electricity or sparks, it will cause danger. And during transportation, it should be protected from exposure to the sun, rain, and high temperature. During the journey, the environment is complex, and exposure to the hot sun or rain may change its physical and chemical properties. In addition, it is strictly forbidden to mix with oxidants, alkalis, etc. This is the same as the storage requirements, all to avoid dangerous reactions. When loading and unloading, it should be handled lightly to prevent damage to packaging and containers. If the packaging is damaged and the material leaks, it will not only waste resources, but also pose a threat to the environment and personnel safety.